THE MECHANISM OF THE NORRISH TYPE II REACTION OF α-KETO-ACIDS AND ESTERS

DOI: 10.1016/S0040-4039(01)92939-9

Source and publish data:

Tetrahedron Letters p. 2485 - 2486 (1981)

Update date:2022-08-05

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Authors:

Davidson, R. Stephen

Goodwin, Dean

Violet, Ph. Fornier de

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Article abstract of DOI:10.1016/S0040-4039(01)92939-9

Methyl-α-keto-octanoate undergoes a Type II reaction to give pent-1-ene and photophysical measurements show that this and the Type II reactions of α-keto-acids occur, contrary to previous claims, from the excited singlet state.

Full text of DOI:10.1016/S0040-4039(01)92939-9

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