REGIO- AND STEREO-SELECTIVE ALKYLATION OF 3-TRIMETHYLSILYLMETHYL DIENOLATES. A NOVEL SYNTHESIS OF 3-ALKYLATED 2-METHALLYLSILANES.

DOI: 10.1016/S0040-4039(01)90413-7

Source and publish data:

Tetrahedron Letters p. 1691 - 1694 (1981)

Update date:2022-08-05

Topics:

Authors:

Nishiyama, Hisao

Itagaki, Kazuyoshi

Takahashi, Kaoru

Itoh, Kenji

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Article abstract of DOI:10.1016/S0040-4039(01)90413-7

Lithium and copper 3-trimethylsilylmethyl dienolate anions derived from easily available 3-trimethylsilylmethyl-3-butenoic acid and its methyl ester underwent regio- and stereo-selective alkylation. α-Alkylated products were readily transformed to 3-alkylated 2-methallylsilanes by pyrolysis.

Full text of DOI:10.1016/S0040-4039(01)90413-7

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