Tetrahedron Letters p. 1691 - 1694 (1981)
Update date:2022-08-05
Topics:
Nishiyama, Hisao
Itagaki, Kazuyoshi
Takahashi, Kaoru
Itoh, Kenji
Lithium and copper 3-trimethylsilylmethyl dienolate anions derived from easily available 3-trimethylsilylmethyl-3-butenoic acid and its methyl ester underwent regio- and stereo-selective alkylation. α-Alkylated products were readily transformed to 3-alkylated 2-methallylsilanes by pyrolysis.
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(1986)
