ELECTRON TRANSFER INITIATED PHOTOCYCLIZATIONS OF N-ALLYLPYRIDINIUM AND QUINOLINIUM SALTS

DOI: 10.1016/S0040-4039(00)86983-X

Source and publish data:

Tetrahedron Letters p. 919 - 922 (1982)

Update date:2022-07-29

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Authors:

Yoon, Ung Chan

Quillen, Suzanne L.

Mariano, Patrick S.

Swanson, Rosemarie

Stavinoha, Jerome L.

Bay, Elliott

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Article abstract of DOI:10.1016/S0040-4039(00)86983-X

Results from study of the photochemistry of N-allylpyridinium and -quinolinium perchlorates demonstrate that intramolecular electron transfer occurs to generate cation diradical precursors of products containing the tetrahydroindolizidine moiety.Catalytic hydrogenation of the crude photolysates leads to production of perhydroindolizidines in synthetically useful yields.

Full text of DOI:10.1016/S0040-4039(00)86983-X

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