Transition Metal Complexes with Bidentate Ligands Spanning trans-Positions. XII. The Preparation and Properties of Complexes trans- and trans- (M=Ni, Pd and Pt; X=Cl and NCS; 1=ditertiary phosphine)

DOI: 10.1002/hlca.19820650304

Source and publish data:

Helvetica Chimica Acta p. 654 - 660 (1982)

Update date:2022-09-26

Topics:

Authors:

Kapoor, Pramesh N.

Pregosin, Paul S.

Venanzi, Luigi M.

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Article abstract of DOI:10.1002/hlca.19820650304

Complexes (M=Ni, Pd and Pt; X=Cl and NCS; 1= 2,11-bis(dialkyl- phosphinomethyl)benzophenanthrene; alkyl= cyclohexyl t-butyl; aryl= m-tolyl, p-anisyl and m-CF3-C6H4) have been synthesized.An NMR. study of the t-butyl complexes provides evidence for a fan-like motion of the benzophenanthrene moiety over the plane of the complex.

Full text of DOI:10.1002/hlca.19820650304

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