ACYLATION REACTIONS OF SILYLATED BUTADIYNES: SYNTHESIS OF SOME NATURALLY OCCURRING DIACETYLENIC KETONES

DOI: 10.1016/S0040-4039(00)88596-2

Source and publish data:

Tetrahedron Letters p. 3203 - 3206 (1982)

Update date:2022-08-04

Topics:

Authors:

Jones, Graham E.

Holmes, Andrew B.

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Article abstract of DOI:10.1016/S0040-4039(00)88596-2

Acylation of 4-substituted 1-trimethylsilylbuta-1,3-diynes (2) with suitable acyl halides in the presence of titanium tetrachloride gave diacetylenic ketones (3) including the naturally occurring compounds (3c), (3e), and (3f).

Full text of DOI:10.1016/S0040-4039(00)88596-2

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