ACYLATION REACTIONS OF SILYLATED BUTADIYNES: SYNTHESIS OF SOME NATURALLY OCCURRING DIACETYLENIC KETONES

DOI: 10.1016/S0040-4039(00)88596-2

Source and publish data:

Tetrahedron Letters p. 3203 - 3206 (1982)

Update date:2022-08-04

Topics:

Authors:

Jones, Graham E.

Holmes, Andrew B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88596-2

Acylation of 4-substituted 1-trimethylsilylbuta-1,3-diynes (2) with suitable acyl halides in the presence of titanium tetrachloride gave diacetylenic ketones (3) including the naturally occurring compounds (3c), (3e), and (3f).

Full text of DOI:10.1016/S0040-4039(00)88596-2

Products guided by the article

Product name:(Z)-1-Phenyl-hept-4-en-2-yn-1-one

Cas No:83670-27-3

R&D Labs maybe for 83670-27-3

Kunming Biohome Technology Co. Ltd.

website:http://www.biohometech.com/

Contact:86-871-67428869

Address:kunming
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Jinan Jianfeng Chemical Co., Ltd

Contact:0086-531-88110457

Address:sales01(-a-t-)pharmachemm{dot}c+o+m

Relevant to this article

Alkyl halide-free heteroatom alkylation and epoxidation facilitated by a recyclable polymer-supported oxidant for the in-flow preparation of diazo compounds

Doi:10.1002/chem.201500118
(2015)
Orally active purine-based inhibitors of the heat shock protein 90

Doi:10.1021/jm0503087
(2006)
1,10-Phenanthroline-catalyzed tandem reaction of 2-iodoanilines with isothiocyanates in water

Doi:10.1002/adsc.201200175
(2012)
Design, synthesis, and evaluation of original carriers for targeting vascular endothelial growth factor receptor interactions

Doi:10.1007/s11095-005-5265-9
(2005)
Access to Branched Allylarenes via Rhodium(III)-Catalyzed C-H Allylation of (Hetero)arenes with 2-Methylidenetrimethylene Carbonate

Doi:10.1021/acs.orglett.1c01832
(2021)
Phosphane-catalyzed reactions of LAlH₂ with elemental chalcogens; preparation of [LAl(μ-E)₂AlL] [E = S, Se, Te, L = HC{C(Me)N(Ar)}₂, Ar = 2,6-iPr₂C₆H₃]

Doi:10.1002/ejic.200400062
(2004)

Article Doi