Bulletin of the Chemical Society of Japan p. 99 - 104 (1983)
Update date:2022-08-05
Topics:
Kanatomi, Hajime
Nickel(II) acetate tetrahydrate and rac- and meso-2,2'-<(1,2-diphenylethylene)bis(iminomethylene)>diphenol (rac- and meso-BzPhen-H2) formed pale green complexes in methanol.A pyridine solution of these complexes deposited deep red diimine complexes after prolonged heating under aerobic conditions.The saturated ligand system of the initial complexes was dehydrogenated to an unsaturated one by molecular oxygen.From the pyridine solution of the meso-isomer, <2,2'-<(cis-1,2-diphenylethenylene)bis(nitrilomethylidyne)>diphenolato>nickel(II) (
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