Chemistry Letters p. 1823 - 1824 (1982)
Update date:2022-08-05
Topics:
Sakakibara, Tsutomu
Hamakawa, Tomoko
Intermediates in reaction of N,N-dimethylanilines with palladium(II) acetate were trapped by acetate ion or oxygen to give N-methyloxygenated and demethylated products, while the trapping by other anilines gave homo- and cross-coupling cyclodimers.The reactions proceed via radical cation formation induced by the palladium salt.
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