REGIOSPECIFIC α-HEXAFLUOROISOPROPYLIDENATION OF KETONES USING HEXAFLUOROACETONE

DOI: 10.1016/S0022-1139(00)81485-2

Source and publish data:

Journal of Fluorine Chemistry p. 1 - 20 (1983)

Update date:2022-07-29

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Authors:

Ishihara, Takashi

Shinjo, Hiroshi

Inoue, Yoshihisa

Ando, Teiichi

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Article abstract of DOI:10.1016/S0022-1139(00)81485-2

Hexafluoroacetone (HFA) reacted regiospecifically with various enol silyl ethers at -30 to -35 deg C in the presence of a Lewis acid to give HFA aldols, or α-bis(trifluoromethyl)hydroxymethyl carbonyl compounds, in good yields.The reaction of HFA with die

Full text of DOI:10.1016/S0022-1139(00)81485-2

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