Journal of Organic Chemistry p. 2503 - 2505 (1983)
Update date:2022-08-05
Topics:
Shono, Tatsuya
Nishiguchi, Ikuzo
Sasaki, Manji
Ikeda, Haruhiko
Kurita, Makoto
It was found that acylation of a variety of aliphatic olefins with acid chlorides is efficiently promoted by active zinc compounds, which were prepared from a Zn/Cu couple and alkyl iodides.The crude product mixtures were subsequently treated with 1 M KOH in methanol or were subjected to catalytic hydrogenation to afford the corresponding α,β-unsaturated or saturated ketones in good to moderate yields.It was also shown that the reaction fully follows the Markovnikov rule.
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(1940)Doi:10.1016/S0040-4020(01)91103-2
(1984)Doi:10.1021/ja01217a044
(1945)Doi:10.1039/jr9350001123
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(2005)
