Journal of Organic Chemistry p. 2503 - 2505 (1983)
Update date:2022-08-05
Topics:
Shono, Tatsuya
Nishiguchi, Ikuzo
Sasaki, Manji
Ikeda, Haruhiko
Kurita, Makoto
It was found that acylation of a variety of aliphatic olefins with acid chlorides is efficiently promoted by active zinc compounds, which were prepared from a Zn/Cu couple and alkyl iodides.The crude product mixtures were subsequently treated with 1 M KOH in methanol or were subjected to catalytic hydrogenation to afford the corresponding α,β-unsaturated or saturated ketones in good to moderate yields.It was also shown that the reaction fully follows the Markovnikov rule.
View MoreZhejiang kehong chemical co., ltd
Contact:0086-575-85522000
Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Jinan Jiaquan Chemical Co.,Ltd
Contact:+86-531-62318366
Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Contact:18669908765
Address:Zibo City, Shandong Province, P.R.China
Kaymossy BioChem Tech Co., Ltd
website:http://www.kaimosi.com
Contact:0571-87191913/0571-87199097
Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
Doi:10.1021/ja01861a037
(1940)Doi:10.1016/S0040-4020(01)91103-2
(1984)Doi:10.1021/ja01217a044
(1945)Doi:10.1039/jr9350001123
(1935)Doi:10.1007/BF01516747
(1888)Doi:10.1016/j.bmcl.2005.05.082
(2005)