SYNTHESIS OF PYRROLIDINES USING AN α-CYANOAMINOSILANE AS AN AZOMETHINE YLIDE EQUIVALENT

DOI: 10.1016/S0040-4039(00)86009-8

Source and publish data:

Tetrahedron Letters p. 3447 - 3450 (1983)

Update date:2022-08-05

Topics:

Authors:

Padwa, Albert

Chen, Yon-Yih

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)86009-8

The potential of α-cyanoaminosilane (3) to act as an azomethine ylide equivalent is illustrated by its treatment with silver fluoride in the presence of electron deficient olefins to give substituted pyrrolidines in high yield.

Full text of DOI:10.1016/S0040-4039(00)86009-8

Products guided by the article

Product name:(3R,4S)-3-Benzo[1,3]dioxol-5-yl-1-benzyl-4-nitro-pyrrolidine

Cas No:87813-04-5

R&D Labs maybe for 87813-04-5

Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Chongqing Kangheyuecheng Pharmaceutical Technology Co., LTD

Contact:86+023-61183015-18725809730

Address:Degan Industrial Park Jiangjin Chongqing City
Shandong Xinhua Pharmaceutical Co.,Ltd

website:http://www.xhzy.com

Contact:+86-533-2196801

Address:1 lutai road,zhangdian dis,Zibo City
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
SUZHOU CHEMWELLS ADVANCED MATERIALS CO.,LTD.

website:http://www.chemwells.com

Contact:+86-512-53202808

Address:Xiangtang-Dewei Building, No.168 Shanghai East Road, Taicang City

Relevant to this article

The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands

Doi:10.1016/j.ica.2005.06.044
(2006)
Structure-activity relationship study of copper(II) complexes with 2-oxo-1,2-dihydroquinoline-3-carbaldehyde (4'-methylbenzoyl) hydrazone: Synthesis, structures, DNA and protein interaction studies, antioxidative and cytotoxic activity

Doi:10.1007/s00775-011-0844-1
(2012)
Synthesis and biological characterization of [³H] (2-amino-4,5,6,7-tetrahydrobenzo[b]thiophen-3-yl)-(4-chlorophenyl)-methanone, the first radiolabelled adenosine A₁ allosteric enhancer

Doi:10.1016/j.bmcl.2005.11.037
(2006)
Improved stereoselectivity in intramolecular S_N2′ cyclization through use of mechanistic principles

Doi:10.1055/s-2006-958956
(2007)
Intermolecular [4 + 2] cycloaddition of o-quinodimethanes derived from ene-bis(sulfinylallenes)

Doi:10.1021/jo061014b
(2006)
Temperature switchable Br?nsted acid-promoted selective syntheses of spiro-indolenines and quinolines

Doi:10.1039/c7cc02580g
(2017)

Article Doi