A NEW SYNTHESIS OF α-METHYLENE CARBONYL COMPOUNDS

DOI: 10.1016/S0040-4039(00)86017-7

Source and publish data:

Tetrahedron Letters p. 3477 - 3480 (1983)

Update date:2022-08-02

Topics:

Authors:

Ono, Noboru

Miyake, Hideyoshi

Fujii, Masayuki

Kaji, Aritsune

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Article abstract of DOI:10.1016/S0040-4039(00)86017-7

α-Methylene carbonyl compounds are regioselectively prepared by the reaction of α-nitroketones or α-nitroesters with 37percent formaldehyde in the presence of a catalytic amount of weak bases followed by acetylation, denitration with Bu₃SnH, and elimination of acetic acid.

Full text of DOI:10.1016/S0040-4039(00)86017-7

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