Intramolecular Olefin Epoxidation observed in the Air Oxidation of 1-Phenyl-1-diazopent-4-ene Derivatives

DOI: 10.1039/c39840000147

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 147 - 148 (1984)

Update date:2022-08-05

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Authors:

Miyashi, Tsutomu

Kamata, Masaki

Nishizawa, Yoshinori

Mukai, Toshio

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Article abstract of DOI:10.1039/c39840000147

The simple air oxidation of 1-phenyl-1-diazopent-4-ene derivatives (2) under basic conditions (NaH) was found to involve an efficient intramolecular epoxidation to give epoxyketone (3), while the dye-sensitised photo-oxygenation reaction of (2) afforded k

Full text of DOI:10.1039/c39840000147

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