
Chemistry Letters p. 157 - 160 (1986)
Update date:2022-08-04
Topics:
Kumobayashi, Hidenori
Mitsuhashi, Shigeru
Akutagawa, Susumu
Ohtsuka, Sei
A Palladium complex-catalyzed elimination reaction of allyl amines was studied to establish a practical process for production of myrcenol.The catalytic elimination occurred smoothly with the cationic Pd(II) complexes.Among a variety phosphorous ligands, the tetramethylene and the pentamethylene diphosphine ligands proved to be the best ligand with respects to the catalytic activity and selectivity.
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