Journal of Organometallic Chemistry p. 115 - 122 (1984)
Update date:2022-08-03
Topics:
Sarlo, Francesco De
Guarna, Antonio
Goti, Andrea
Brandi, Alberto
Organomercury fulminates react with acetylene derivatives to give unstable 3-(organomercurio)isoxazoles, which isomerize to 2-cyanoenolates.These are hydrolyzed with hydrochloric acid to the corresponding enols and are cleaved by water at the double bond.With monosubstituted acetylenes, substitution at the free position by the organomercury residue is predominant.
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(1984)
