Rearrangement of the carbanion generated from a tied-back 1,2,4- trithiolane oxide (6,7,8-trithiabicyclo[3.2.1]octane 6-oxide)

DOI: 10.1016/S0040-4020(99)00589-X

Source and publish data:

Tetrahedron p. 10341 - 10350 (1999)

Update date:2022-08-04

Topics:

Authors:

Ishii, Akihiko

Nakaniwa, Tetsuya

Umezawa, Kazuyo

Nakayama, Juzo

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Article abstract of DOI:10.1016/S0040-4020(99)00589-X

Treatment of 2,2,4,4-tetramethyl-6,7,8-trithiabicyclo[3.2.1]octane 6- exo-oxide (3) with LDA, followed by treatment with D₂O, R1 (R = Me, Et), and 2-PrBr, yielded the deuterated starting compound (3-d), bicyclic 1,3- dithietane oxides (12, 13),

Full text of DOI:10.1016/S0040-4020(99)00589-X

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