Tetrahedron p. 435 - 450 (1985)
Update date:2022-08-05
Topics: Oxidation Regioselectivity Kinetic studies Reduction Chromatography Retro-aldol reaction Nucleophilic Attack Stereoselectivity Ring Expansion Spectroscopic Analysis Thermodynamic Control Tautomerization Electrophilic addition Ring contraction Acid-catalyzed rearrangement 1,2-hydride shift
novak
Szantay
Meisel
Aszodi
Szabo
fekete
Novel rearrangements of hydroxycyclopentenone derivatives 1 and 24 to 7,9,11 and 31,33,35 are reported. The stereochemistry of the rearrangement is interpreted as the result of synchronous enolate induced [1.5]-sigmatropic rearrangement and stepwise addition-elimination process. Preparation of the various substrates and structural elucidation of new products are also described.
View MoreZhejiang Chemicals Import & Export Corporation (ZHECHEM)
Contact:+86-571-87046953
Address:No. 37, Qingchun Road
Zouping Mingxing Chemical Co.,Ltd.
website:http://www.zoutong.com.cn
Contact:86-543-2240068 2240067
Address:428 Daixi Third Road Zouping County Shandong Province China
website:https://www.synose.com/
Contact:86-579-82275537
Address:No.1958 Liyu Road , jinhua,zhejiang,China
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.
Contact:15967177856
Address:Genglou Industrial Development Area
Contact:86-379-63338609
Address:Jiudian Village,Deting Town,Song County,Luoyang
Doi:10.1021/ja01063a037
(1964)Doi:10.1071/CH18559
(2019)Doi:10.1021/acs.inorgchem.0c02121
(2020)Doi:10.1021/ja00334a081
(1984)Doi:10.1021/ja01561a044
(1957)Doi:10.1016/S0020-1693(00)87481-2
(1985)
