Pesticide Science p. 305 - 310 (1994)
Update date:2022-08-10
Topics:
Kamiya, Mamoru
Nakamura, Kaori
The inhibition of alkaline hydrolysis of organophosphorothioate pesticides such as parathion, parathion-methyl and fenitrithion by the formation of inclusion complexes with β-cyclodextrin and its methylated derivatives was investigated. The inclusion complex/pesticide stability relationship with the series of pesticides and β-cyclodextrins is discussed in connection with the inclusion geometrical parameters, such as those relating to the inclusion orientation and depth of the 4-nitrophenoxy moiety of the included pesticide. These parameters were estimated from the induced circular dichroism of the inclusion complexes by means of the rotational-strength analysis method.
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