Tetrakis(pyridine)silver(II) Peroxodisulfate, S2O8, a Reagent for the Oxidative Transformations

DOI: 10.1246/bcsj.65.2878

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2878 - 2880 (1992)

Update date:2022-08-11

Topics:

Authors:

Firouzabadi, Habib

Salehi, Peyman

Mohammadpour-Baltork, Iraj

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Article abstract of DOI:10.1246/bcsj.65.2878

Tetrakis(pyridine)silver(II) peroxodisulfate oxidizes aromatic aldehydes to carboxylic acids, benzylic alcohols to carbonyl compounds, aromatic thiols, and allylaryl thioethers to arylsulfonic acids and benzylic carbon-hydrogen bonds to carbonyl groups. α-Hydroxycarboxylic acids and phenylacetic acids are decarboxylated to produce carbonyl compounds.Dibenzyl ether and its sulfur analogue are converted to their corresponding ester and the thioester, respectively.

Full text of DOI:10.1246/bcsj.65.2878

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