Russian Chemical Bulletin p. 1479 - 1483 (1994)
Update date:2022-08-30
Topics:
Shereshovets, V. V.
Korotaeva, N. M.
Vorob'ev, A. S.
Komissarov, V. D.
Furlei, I. I.
The reaction of triphenyl phosphite ozonide with various types of diazo compounds results in their oxidation, which is accomplished by singlet oxygen (1O2) evolved during thermal decomposition of the ozonide.A decrease in the ionization potential of the substrate results in an increase in the overall rate constant of quenching of 1O2.In the case of 9-diazofluorene, the main channel of 1O2 quenching is physical quenching. - Key words: phosphite ozonides, singlet oxygen; diazo compounds; ionization potential; rate constant of quenching of singlet oxygen.
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