Addition of tert-Butyldimethyl- or tert-Butyldiphenylsilyl Cyanide to Hindered Ketones

DOI: 10.1021/jo00053a030

Source and publish data:

Journal of Organic Chemistry p. 159 - 164 (1993)

Update date:2022-08-31

Topics:

Authors:

Golinski, Miroslaw

Brock, Carolyn P.

Watt, David S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00053a030

The addition of trimethylsilyl cyanide (TMSCN), tert-butyldimethylsilyl cyanide (TBDMSCN) or tert-butyldiphenylsilyl cyanide (TBDPSCN) to sterically hindered ketones proceeded in good yield under catalysis by Lewis acids (ZnI2, CH2Cl2, 25 deg C) or bases

Full text of DOI:10.1021/jo00053a030

Products guided by the article

Product name:C₁₇H₂₅NOSi

Cas No:100573-23-7

R&D Labs maybe for 100573-23-7

shanghai meicheng chemical co .,ltd(expird)

Contact:+86-21-50677091

Address:Room 302, Building 7, No.1000, Jinhai Road
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Tradlon Chemical Co., Ltd.

Contact:+86-710-3516804

Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Zibo Kunran Enterprises Co. LTD

website:http://www.kunranchem.com

Contact:0086 533 5200669

Address:No. 96 Jinjing Avenue, Zibo, Shandong, China

Relevant to this article

Gas-phase deprotonation of p-hydroxybenzoic acid investigated by IR spectroscopy: Solution-phase structure is retained upon ESI

Doi:10.1021/ja903877v
(2009)
New dimeric anthracenyl-derived Cinchona quaternary ammonium salts as phase-transfer catalysts for the asymmetric synthesis of α-amino acids

Doi:10.1016/S0957-4166(02)00211-2
(2002)
Resolution-free route to chiral 2,2′-bis(pyridin-2-yl)-1,1′- binaphthyl ligand: Photochemical CpCo(CO)₂-mediated cycloaddition of enantiopure 2,2′-dicyano-1,1′-binaphthyl with diynes

Doi:10.1016/j.tetlet.2004.02.155
(2004)
Doi:10.1039/c39720000424
(1972)
Larrealignans A and B, novel lignan glycosides from the aerial parts of Larrea tridentata

Doi:10.1248/cpb.59.1467
(2011)
Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (η⁵-C₅Me₅)M{(R)-Prophos} containing complexes (M = Rh, Ir; (R)-Prophos = 1,2-bis(diphenylphosphino) propane): On the origin of the enantio

Doi:10.1021/ja0539443
(2005)

Article Doi