Addition of tert-Butyldimethyl- or tert-Butyldiphenylsilyl Cyanide to Hindered Ketones

DOI: 10.1021/jo00053a030

Source and publish data:

Journal of Organic Chemistry p. 159 - 164 (1993)

Update date:2022-08-31

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Authors:

Golinski, Miroslaw

Brock, Carolyn P.

Watt, David S.

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Article abstract of DOI:10.1021/jo00053a030

The addition of trimethylsilyl cyanide (TMSCN), tert-butyldimethylsilyl cyanide (TBDMSCN) or tert-butyldiphenylsilyl cyanide (TBDPSCN) to sterically hindered ketones proceeded in good yield under catalysis by Lewis acids (ZnI2, CH2Cl2, 25 deg C) or bases

Full text of DOI:10.1021/jo00053a030

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