The nonadiabatic photodissociation of BrNO at 355 nm

Article abstract of DOI:10.1063/1.467586

Nozzle cooled BrNO molecules were dissociated with a polarized laser at 355 nm.The NO fragments were then state-selectively probed using a second tunable laser.Resonance-enhanced multiphoton ionization and fragment time-of-flight techniques were combined to obtain scalar and vector properties of the NO fragment.For each of the NO states probed, the Br^*/Br ratio was determined.From these data, a comprehensive picture of the dissociation process was obtained.The excitation at 355 nm has a transition dipole moment parallel to the Br-N bond (β ca. 2.0).The NO fragment was observed with high rotational excitation (J ca. 50) and nonstatistical spin-orbit and Λ-doublet state distributions.

Full text of DOI:10.1063/1.467586

The nonadiabatic photodissociation of BrNO at 355 nm
Jianying Cao, HansPeter Loock, and Charles X. W. Qian
Citation: The Journal of Chemical Physics 101, 3395 (1994); doi: 10.1063/1.467586
View online: http://dx.doi.org/10.1063/1.467586
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/101/4?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.112.220.156 On: Tue, 16 Dec 2014 16:30:10

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.112.220.156 On: Tue, 16 Dec 2014 16:30:10

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.112.220.156 On: Tue, 16 Dec 2014 16:30:10

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.112.220.156 On: Tue, 16 Dec 2014 16:30:10