Chemical Physics Letters p. 9 - 15 (1995)
Update date:2022-08-16
Topics:
Bhatnagar, Ashish
Carr, Robert W.
The kinetics of the reaction of CF3CFHO2 radicals with NO was studied by flash photolysis-time-resolved mass spectrometry.From the kinetic growth rate of NO2+ molecular ions the rate coefficient of the reaction CF3CFHO2 + NO --> CF3CFHO + NO2 was determined to be k = (1.31+/-0.30)x10-11 cm3 molecule-1 s-1 in the pressure range 12-25 Torr at 324 +/- 1 K.Measurements of the total NO2 yield indicated that CF3CFHO radicals were completely dissociated by C-C bond scission on the 50 ms time scale of the experiments.The results are discussed in the context of atmospheric chemistry of HFC-134a.
View More
Zhejiang Kaili Industrial Co., Ltd
Contact:+86-571-85241926
Address:lantian business center,No.18 Moganshan Road
shijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Contact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Contact:+86 021-51698675
Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
Contact:+86-913-2223392
Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Doi:10.1021/j100264a003
(1985)Doi:10.1007/BF02659537
()Doi:10.1055/s-0037-1611847
(2019)Doi:10.1039/c8nj01150h
(2018)Doi:10.1021/jacs.6b03599
(2016)Doi:10.1021/acs.cgd.0c01694
(2021)
