REACTIONS OF γ-ACYLOXY-β-KETOPHOSPHONATES: NEW ROUTES TO 3(2H)- AND 2(3H)-DIHYDROFURANONES

DOI: 10.1016/S0040-4039(01)81468-4

Source and publish data:

Tetrahedron Letters p. 4467 - 4470 (1984)

Update date:2022-08-17

Topics:

Authors:

Drtina, Gary J.

Sampson, Paul

Wiemer, David F.

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Article abstract of DOI:10.1016/S0040-4039(01)81468-4

Depending on the reaction conditions, γ-acyloxy-β-ketophosphonate anions can undergo either an intramolecular Wittig-like condensation or an unexpected rearrangement which affords an enol ester product.

Full text of DOI:10.1016/S0040-4039(01)81468-4

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