Bulletin of the Chemical Society of Japan p. 1984 - 1986 (1994)
Update date:2022-08-28
Topics:
Sakai, Mutsuji
Takai, Yoshihiro
Mochizuki, Hiroki
Sasaki, Ken
Sakakibara, Yasumasa
Under an atmospheric pressure of hydrogen alkynes were successively hydrogenated to give alkanes via (Z)-alkenes with the metallic nickel catalyst, which was easily prepared by reaction of nickel bromide with zinc powder.Phosphines and diamines as catalyst modifiers were effective for the partial hydrogenation of alkynes.
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