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ACS Catalysis
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important role for THFDM conversion. Nearly the same
Werle, P.; Morawietz, M.; Lundmark, S.; Sorensen,
K.; Karvinen, E.; Lehtonen, J. in Ullmann’s
Encyclopedia of Industrial Chemistry, 2008, 263–
281.
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THFDM conversion is obtained from the physical mixꢀ
ture of Pt/TiO and WO /TiO , due to the hydrogen
2
x
2
spillover with spatially separate Pt/TiO and WO /TiO .
2
x
2
Low catalytic activity is observed with physical mixꢀ
tures of WO /TiO with Pt/C or Pt/Al O . The synergisꢀ
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Faber, M. US 4,400,468, 1983.
x
2
2
3
tic effect between Pt and WO is required for the high
x
Buntara, T.; Noel, S.; Phua, P. H.; MelianꢀCabrera,
I.; De Vries, J. G.; Heeres, H. J. Angew. Chemie -
Int. Ed., 2011, 50, 7083–7087.
activity and selectivity of PtꢀWO /TiO and is facilitated
x
2
by the reducible support.
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Daorattanachai, P.; Namuengruk, N.; Viriyaꢀ
Empikul, N.; Laosiripojana, N.; Faungnawakij, K.
J. Ind. Eng. Chem., 2012, 18, 1893–1901.
ꢀ
Supplementary Information
Catalyst Synthesis techniques, as well as synꢀ
thesis technique of THFDM from HMF, are listed in the
Supporting Information. Tables S1ꢀS3 and Figures S1ꢀ
S10 can also be found there.
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Yin, S.; Pan, Y., Tan, Z. Int. J. Green Energy,
2011, 8, 234–247.
ꢀ
Acknowledgements
Kuster, B. F. M. Starch-Starke, 1990, 42, 314–321.
This material is based upon work supported by
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Buntara, T.; Noel, S.; Phua, P. H.; MelianꢀCabrera,
I.; De Vries, J. G.; Heeres, H. J. Top. Catal., 2012,
the Department of Energy, Office of Energy Efficiency
and Renewable Energy (EERE), under Award Number
DEꢀEE0006878. Any opinions, findings, and concluꢀ
sions or recommendations expressed in this material are
those of the authors and do not necessarily reflect the
views of the Department of Energy. We thank Phoebe
Wagner, Xiaoli Chen, Giulia Kitayama Canhetti Mondin
for assistance with THFDM and catalyst synthesis and
Daniel McClelland for the NMR experiments and analyꢀ
sis. The authors acknowledge use of instrumentation
supported by UW MRSEC (DMRꢀ1121288) and the
UW NSEC (DMRꢀ0832760).
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Unsaturated
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