
Tetrahedron p. 17171 - 17176 (1997)
Update date:2022-08-18
Topics:
Venkatachalapathy, Chockalingam
Pitchumani, Kasi
In the Fries rearrangement of phenyl and naphthyl esters in clay interlayer, framework aluminium acts as a Lewis acid, catalysing the rearrangement. An increase in the size of migrating group/substrate causes an increase in the formation of 2-isomer.
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