Wavelength Dependence of Photocatalytic Cyclohexane Dehydrogenation by Carbonyl- and Thiocarbonyl-(chloro)-phosphine Rhodium(I) Complexes

DOI: 10.1039/DT9910001093

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1093 - 1097 (1991)

Update date:2022-08-17

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Authors:

Iwamoto, Aki

Itagaki, Hiroaki

Saito, Yasukazu

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Article abstract of DOI:10.1039/DT9910001093

Photocatalytic dehydrogenation of cyclohexane using was closely related to photodissociation of the CS ligand, where the effective absorption band was not of the lowest energy but the second lowest, in contrast to the CO analogue.The estimated turnover number of in the dehydrogenation cycle was 3.8 on the assumption that is photodecomposed irreversibly.The wavelength dependence of photocatalysis by these complexes is well interpreted in terms of the molecular-orbital energy levels and orbital interactions.

Full text of DOI:10.1039/DT9910001093

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