
Synthetic Communications p. 2865 - 2876 (1997)
Update date:2022-08-16
Topics:
Berthelot, Jacques
Benammar, Yamina
Desmazieres, Bernard
The reaction of tetrabutylammonium tribromide (TBABr3) with mono and disubstituted alkynes in methanol at 20°C leads to the formation of mainly the corresponding α,α-dibromo, β,β-dimethoxyalkane and the E-(α,β)- dibromoalkene. The additions are faster using sonication.
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