Pd-catalyzed coupling reaction of acetylenes, iodotrimethylsilane, and organozinc reagents for the stereoselective synthesis of vinylsilanes

DOI: 10.1021/jo00111a048

Source and publish data:

Journal of Organic Chemistry p. 1834 - 1840 (1995)

Update date:2022-08-16

Topics:

Authors:

Chatani Chatani

Amishiro

Morii Morii

Yamashita

Murai Murai

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Article abstract of DOI:10.1021/jo00111a048

The reaction of terminal acetylenes with Me₃SiI (1) and organozinc reagents in the presence of Pd(PPh₃)₄ results in addition of the trimethylsilyl group of 1 and an alkyl group of the organozinc reagent to the acetylenes.

Full text of DOI:10.1021/jo00111a048

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