The thiazolium catalyzed benzoin condensation with mild base does not involve a 'dimer' inermediate

DOI: 10.1016/S0040-4039(00)75794-7

Source and publish data:

Tetrahedron Letters p. 699 - 702 (1994)

Update date:2022-08-31

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Authors:

Breslow Breslow

Kim Kim

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Article abstract of DOI:10.1016/S0040-4039(00)75794-7

Kinetic studies show that the benzoin condensation catalyzed by 3,4,5-trimethylthiazolium iodide and triethylamine in DMSO has a transition state with two benzaldehyde and one thiazolium components, while the conversion of nitrobenzaldehyde to the thiazol

Full text of DOI:10.1016/S0040-4039(00)75794-7

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