Tetrahedron Letters p. 4759 - 4760 (1981)
Update date:2022-08-17
Topics:
Isaacs, Neil S.
Heremans, Karel A.H.
The rate of oxidation of benzhydrol and benzhydrol-d to benzophenone by alkaline permanganate has been measured over a pH range 10 to 12.5 and pressures from 1 to 1000 bar.The pressure effect on the rate is small, <*>= -6 to -8 cm3mol-1.This is held to support a hydrogen atom transfer in the rate-determining step.
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(2017)
