Tetrahedron Letters p. 4263 - 4266 (1984)
Update date:2022-08-23
Topics:
Herbert, Richard B.
Mann, Jonathan
(2S)-Tyrosine (5) is incorporated stereospecifically into tuberin (1) with retention of the 3-pro-S proton and incomplete retention of the 2-S proton; a parallel pathway to the xanthocillin (4) is apparent with stereospecific retention of the 3-pro-R proton of tyrosine; results of experiments with threo- and erythro-3-hydroxytyrosine in relation to tuberin biosynthesis are reported.
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