Journal of Physical Chemistry p. 1610 - 1614 (1993)
Update date:2022-08-11
Topics:
Lind, Johan
Jonsson, Mats
Eriksen, Trygve E.
Merenyi, Gabor
Eberson, Lennart
By means of pulse radiolysis in water, N-chlorosuccinimide (SCl) was reduced in a one-electron step to yield the succinimidyl radicals, S*, via the intermediacy of the radical anion, SCl*-.The rate of ring opening of S* was measured to be 8 x 104 s-1.By equilibrium with Cl2*-/2Cl-, the one-electron reduction potential of S* was determined to be 2.22 +/- 0.02 V vs NHE.From this value and other data, the N-H bond strength in succinimide was calculated to be 118 +/- 3 kcal/mol.
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