Cu(I)/Pd(0)-catalyzed cross-coupling reaction of alkynylsilanes with aryl or alkenyl triflates: "Sila"-Sonogashira-Hagihara coupling

DOI: 10.1246/cl.1997.1233

Source and publish data:

Chemistry Letters p. 1233 - 1234 (1997)

Update date:2022-08-29

Topics:

Authors:

Nishihara, Yasushi

Ikegashira, Kazutaka

Mori, Atsunori

Hiyama, Tamejiro

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Article abstract of DOI:10.1246/cl.1997.1233

Alkynylsilanes reacted with aryl or alkenyl triflates in the presence of 5 mol% of Pd(PPh₃)₄ and 10 mol% of CuCl in DMF to give the corresponding cross-coupling, namely "sila"-Sonogashira-Hagihara coupling, products in good to excell

Full text of DOI:10.1246/cl.1997.1233

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