Chemistry Letters p. 265 - 266 (1998)
Update date:2022-08-16
Topics:
Kurosaka, Tadahiro
Matsuhashi, Hiromi
Arata, Kazushi
An active and stable catalyst of 3 wt% Pt-added sulfated-zirconia for the dehydrogenative coupling of methane is obtained by impregnating zirconia gel with 0.5 mol dm-3 H2SO4 followed by drying, impregnating the sulfated gel with a solution of H2PtCl6, calcining in air at 600°C, and finally reducing in H2 at 500°C; this catalyst gave 40% conversion of the equilibrium value with 100% selectivity at 500°C.
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