Reaction of α,β-Unsaturated Imidates with Grignard Reagents Leading to 2-Alkyl 1,3-Diimines

DOI: 10.1039/c39850001773

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1773 - 1774 (1985)

Update date:2022-07-29

Topics:

Authors:

Inoue, Seiichi

Suzuki, Osamu

Sato, Kikumasa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001773

Methyl N-phenylacrylimidate (1a) reacted with alkyl- and aryl-magnesium bromides in ether at O deg C to give 2-alkyl 1,3-diketones (3a) in a good yield after aqueous work-up; methyl N-phenylcrotonimidate (1b) and N-phenylcinnamimidate (1c) with alkylmagnesium bromides furnished analogous 1,3-diketones (3) as the major products after hydrolysis of the corresponding stable diimines (2).

Full text of DOI:10.1039/c39850001773

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-Heptanone, 5-phenyl-

Cas No:124348-40-9

R&D Labs maybe for 124348-40-9

Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Hangzhou Donglou Bio-nutrient Co., Ltd.

Contact:+86-571-82225795,13967112289

Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang

Relevant to this article

CONVERGENT APPROACH TO INTERMEDIATES USED FOR THE SYNTHESIS OF THE ENEDIYNE STRUCTURE OF THE ESPERAMICINS AND CALICHEAMICINS

Doi:10.1016/S0040-4039(00)99423-1
(1989)
Further delineation of hydrophobic binding sites in dopamine D ₂/D₃ receptors for N-4 substituents on the piperazine ring of the hybrid template 5/7-{[2-(4-aryl-piperazin-1-yl)-ethyl]-propyl-amino}-5, 6,7,8-tetrahydro-naphthalen-2-ol

Doi:10.1016/j.bmc.2010.06.025
(2010)
3-Aryl-4-acyloxyethoxyfuran-2(5H)-ones as inhibitors of tyrosyl-tRNA synthetase: Synthesis, molecular docking and antibacterial evaluation

Doi:10.1016/j.bmc.2013.06.066
(2013)
Synthesis, characterization and theoretical evaluations of HMDS promoted chemoselective O-alkylation of uracils

Doi:10.1016/j.tet.2013.07.025
(2013)
1-Thiacyclooct-4-yne (=5,6-didehydro-3,4,7,8-tetrahydro-2H-thiocin), and its sulfoxide and its sulfone

Doi:10.1002/hlca.201200260
(2013)
Enantioselective synthesis of quaternary 3-aminooxindoles via organocatalytic asymmetric michael addition of 3-monosubstituted 3-aminooxindoles to nitroolefins

Doi:10.1021/jo401154b
(2013)

Article Doi