Improved enantioselection for chiral dirhodium(II) carboxamide-catalysed carbon-hydrogen insertion reactions of tertiary alkyl diazoacetates

DOI: 10.1016/0040-4039(95)00927-5

Source and publish data:

Tetrahedron Letters p. 4745 - 4748 (1995)

Update date:2022-08-18

Topics:

Authors:

Doyle Doyle

Zhou Zhou

Raab Raab

Roos Roos

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00927-5

Enantiocontrol in C-H insertion reactions of 3° alkyl diazoacetates, which is highly dependent on the catalyst ligand, is greatly enhanced with the use of dirhodium(II) tetrakis[methyl 1-acetylimidazolidin-2-one-4(S)-carboxylate), Rh₂(4S-MACIM)₄.

Full text of DOI:10.1016/0040-4039(95)00927-5

Products guided by the article

Product name:2(3H)-Furanone, dihydro-5-methyl-5-(phenylmethyl)-

Cas No:129055-67-0

R&D Labs maybe for 129055-67-0

Hongyi Import & Export CO.,LTD

Contact:86-13319649499

Address:Nanzheng Neighborhood Commitees, Chongwen Office, Yongding District
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.

Relevant to this article

Enhancedcis- And enantioselective cyclopropanation of styrene catalysed by cytochrome P450BM3 using decoy molecules

Doi:10.1039/d0cc04883f
(2020)
The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution

Doi:10.1021/jo802131v
(2009)
A novel synthesis of functional dithioesters, dithiocarbamates, xanthates and trithiocarbonates

Doi:10.1016/S0040-4039(99)00177-X
(1999)
TG and TG-MS methods for studies of the reaction between metal oxide and brominated flame retardant in various atmospheres

Doi:10.1016/j.tca.2011.09.014
(2012)
From Immobilization to Catalyst Use: A Complete Continuous-Flow Approach Towards the Use of Immobilized Organocatalysts

Doi:10.1002/cctc.201901129
(2019)
Studies on the synthesis of 1,2-cis pentofuranosides from S-glycofuranosyl dithiocarbamates, dithiocarbonates and phosphorodithioates

Doi:10.1016/S0008-6215(00)00220-2
(2001)

Article Doi