Natural Product Chemistry, Part 137: Oxidation of Acridone Alkaloids: Synthesis of 5-Methoxyacronycine

DOI: 10.1007/BF00809777

Source and publish data:

Monatshefte fur Chemie p. 709 - 712 (1990)

Update date:2022-08-29

Topics:

Authors:

Reisch, Johannes

Wickramasinghe, Anura

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Article abstract of DOI:10.1007/BF00809777

Epoxidation of acridone alkaloid acronycine (1) resulted in hydroxylation at the aromatic ring giving 5-hydroxyacronycine (3).The same reaction on 1,3-dimethoxy-10-methyl-9(10H)-acridone (5) gave 1,3-dimethoxy-2-hydroxy-10-methyl-9(10H)-acridone (6), 1,3-dimethoxy-2-hydroxy-4-peroxy-10-methyl-9(10H)-acridone (8), and 1,3-dimethoxy-2,4-diperoxy-10-methyl-9(10H)-acridone (9).

Full text of DOI:10.1007/BF00809777

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