Bulletin of the Chemical Society of Japan p. 2161 - 2164 (1982)
Update date:2022-08-11
Topics:
Maruyama, Kazuhiro
Iwamoto, Hidetoshi
Soga, Osamu
Takuwa, Akio
The oxidation of alkyl aryl ketones by t-butyl hydroperoxide under basic conditions gave products which resulted from the fission of the carbon-carbon bond between carbonyl carbon and alkyl carbon.The reaction was investigated using chiral alkyl aryl ketones.On the basis of the results, a probable reaction mechanism is proposed.
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