ACTION DE SILANES PROPARGYLIQUES SUR DES DERIVES CARBONYLES α-ETHYLENIQUES

DOI: 10.1016/S0022-328X(00)87073-4

Source and publish data:

Journal of Organometallic Chemistry p. 177 - 188 (1982)

Update date:2022-08-16

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Authors:

Pornet, Jaques

Kolani, N'Baneyape

Mesnard, Danielle

Miginiac, Leone

Jaworski, Krzysztof

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Article abstract of DOI:10.1016/S0022-328X(00)87073-4

Propargylsilanes RC<*>CCH2Si(CH3)3 easily react with dialkyl alkylidenemalonates, in the presence of TiCl4, to lead to the only product corresponding to an 1,4-addition; the reaction takes place with propargylic rearrangement.

Full text of DOI:10.1016/S0022-328X(00)87073-4

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