
Journal of Organometallic Chemistry p. 177 - 188 (1982)
Update date:2022-08-16
Topics:
Pornet, Jaques
Kolani, N'Baneyape
Mesnard, Danielle
Miginiac, Leone
Jaworski, Krzysztof
Propargylsilanes RC<*>CCH2Si(CH3)3 easily react with dialkyl alkylidenemalonates, in the presence of TiCl4, to lead to the only product corresponding to an 1,4-addition; the reaction takes place with propargylic rearrangement.
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