Journal of Organometallic Chemistry p. 97 - 101 (1997)
Update date:2022-08-28
Topics:
Zhu, Guoxin
Terry, Michael
Zhang, Xumu
A new chiral tridentate ligand containing two phosphines and one pyridine is effective for Ru-catalyzed asymmetric hydrosilylation of simple ketones (47-66% ee). Ruthenium complexes with either chiral tridentate nitrogen ligands or chiral bidentate phosphorus ligands are either inactive or non-selective for asymmetric hydrosilylation. This work has set a foundation for the asymmetric catalytic reactions based on chiral mixed P-N tridentate ligands.
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