Chemistry Letters p. 573 - 576 (1983)
Update date:2022-08-30
Topics:
Okuhara, Toshio
Hashimoto, Tomihito
Misono, Makoto
Yoneda, Yukio
Niiyama, Hiroo
et al.
Transient response method using isotopically labeled isopropanol was applied to confirm the "pseudo-liquid phase" behavior of the dehydration of isopropanol over H3PW12O40.Results were treated by moment analysis.Under the stationary state of catalytic reaction at 80-90 deg C, a large amount of isopropanol was present in the bulk and the absorption-desorption process of isopropanol in the whole bulk was much more rapid than its dehydration to propene, demonstrating the "pseudo-liquid phase" behavior.
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