Bulletin of the Chemical Society of Japan p. 2038 - 2042 (1985)
Update date:2022-08-29
Topics:
Yamamoto, Shunzo
Takahoso, Hiroshi
Sueishi, Yoshimi
Nishimura, Norio
The cadmium-photosensitized reactions of γ-valerolactone and α-methyl-γ-butyrolactone have been investigated.The obtained products in both cases were carbon monoxide, ethylene, propylene, acetaldehyde, and 2-methyloxetane.The dependence of the yields of ethylene and propylene on the total pressure suggests the existence of a biradical and an energized intermediate.Possible mechanisms are discussed.
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Doi:10.1021/jo00361a007
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