ALPHA-DEUTERIUM ISOTOPE EFFECTS IN THE THERMOLYSIS OF β-HYDROXY ESTERS

DOI: 10.1016/S0040-4039(00)76954-1

Source and publish data:

Tetrahedron Letters p. 4735 - 4738 (1994)

Update date:2022-08-30

Topics:

Authors:

Quijano, Jairo

Restrepo, Iliana

Gallego, Luis H.

Yepes, M. del Socorro

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Article abstract of DOI:10.1016/S0040-4039(00)76954-1

Alpha secondary isotope effects are determined experimentally by thermolysis of β-hydroxy esters.These results are compatible with a change of hybridization of carbon-2 from reactant to transition state (sp³-sp²).

Full text of DOI:10.1016/S0040-4039(00)76954-1

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