THE HYDROLYSIS OF BROMODIFLUOROMETHYLTRIPHENYLPHOSPHONIUM BROMIDE

DOI: 10.1016/S0022-1139(00)82669-X

Source and publish data:

Journal of Fluorine Chemistry p. 525 - 532 (1981)

Update date:2022-08-17

Topics:

Authors:

Flynn, R. M.

Manning, R. G.

Kessler, R. M.

Burton, D. J.

Hansen, S. W.

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Article abstract of DOI:10.1016/S0022-1139(00)82669-X

Hydrolysis of ⁺Br^- afforded a high yield of bromodifluoromethane and triphenylphosphine oxide.Hydrolysis in the presence of a radioactive isotope of bromine or sodium iodide gave unequivocal evidence that the mechanism for this reaction proceeds through a difluorocarbene intermediate.

Full text of DOI:10.1016/S0022-1139(00)82669-X

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