A new ruthenium-catalyzed cleavage of a carbon-carbon triple bond: Efficient transformation of ethynyl alcohol into alkene and carbon monoxide

DOI: 10.1021/ja036246w

Source and publish data:

Journal of the American Chemical Society p. 9294 - 9295 (2003)

Update date:2022-08-11

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Authors:

Datta, Swarup

Chang, Chia-Lung

Yeh, Kuo-Liang

Liu, Rai-Shung

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Article abstract of DOI:10.1021/ja036246w

We report a new and efficient ruthenium-catalyzed reaction that transforms ethynyl alcohol into alkene and carbon monoxide. The most efficient catalysts are TpRu(PPh₃)(CH₃CN)₂PF₆ (10 mol %) and lithium triflate

Full text of DOI:10.1021/ja036246w

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