Chlorohydroxylation of Olefins with Peroxides and Titanium Tetrachloride

DOI: 10.1021/jo00206a048

Source and publish data:

Journal of Organic Chemistry p. 912 - 915 (1985)

Update date:2022-08-11

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Authors:

Klunder, Janice M.

Caron, Maurice

Uchiyama, Mamoru

Sharpless, K. Barry

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Article abstract of DOI:10.1021/jo00206a048

TiCl4/TBHP (DTBP) is a powerful reagent for the direct chlorohydroxylation of olefins.Moderate diastereoselectivity has been observed in the reaction of chiral substrates bearing allylic or homoallylic substituents.

Full text of DOI:10.1021/jo00206a048

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