Journal of Organic Chemistry p. 912 - 915 (1985)
Update date:2022-08-11
Topics:
Klunder, Janice M.
Caron, Maurice
Uchiyama, Mamoru
Sharpless, K. Barry
TiCl4/TBHP (DTBP) is a powerful reagent for the direct chlorohydroxylation of olefins.Moderate diastereoselectivity has been observed in the reaction of chiral substrates bearing allylic or homoallylic substituents.
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