Journal of Fluorine Chemistry p. 147 - 153 (1993)
Update date:2022-08-29
Topics:
Munavalli, S.
Rossman, D. I.
Rohrbaugh, D. K.
Ferguson, C. P.
Simultaneous scission of the C-S and S-S bonds of bis(trifluoromethyl)disulfide occurs on treatment with Grignard reagents at -78 deg C and gives rise to unsymmetrical disulfides and sulfides as well as alkyl sulfides.Under similar experimental conditions, alkyl disulfides are recovered unreacted.Probable mechanisms of the cleavage reactions are presented.
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