Journal of the Chemical Society. Chemical communications p. 1754 - 1755 (1992)
Update date:2022-08-11
Topics:
Green, Stuart P.
Whiting, Donald A.
Photolysis of the thiohydroxamate 7 generated the carbon radical 9, which rearranged and aromatised to the methyltetralin 8, providing a model for the biogenesis of the insect antifeedant steroid nic-11 from the conventional C/D precursor nic-3 2: photolysis of the isomeric thiohydroxamate 13 gave both methyltetralins 8 and 14, through an unusual rearrangement sequence, possibly involving the benzvalene related radical 17.
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