Angewandte Chemie - International Edition in English p. 1764 - 1766 (1997)
Update date:2022-08-11
Topics:
Woltering
Frohlich
Hoppe
Three vicinal stereocenters are formed in the (-)-sparteine-induced cyclocarbolithiation of 6-phenyl-5-hexenyl carbamates. The anionic cyclization products can be trapped with various electrophiles (El) to provide enantiomerically pure cyclopentanol derivatives [Eq. (a); Cby = 2,2,4,4-tetramethl-1,3-oxazolidin-3-carboxylate].
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